I guess I'll have to ask a question before I say yes or no. You mean a donation of funds from the bank so the program can purchase cloting? Yes that would qualify. A donation of employees old coats would not.
Also, if you purchase clothing (with bank money) and donate that, the cost of the donation would be qualified (we do this quite often to save chairities time).
Remember that the BANK has to spend money to qualify for the donation. All other thoughts aside, the organization sounds like a pretty slam dunk entity for CD credit if you are putting bank money out to them