When your customer opts in you are not promising to take them overdrawn. If the customer opts in on Tuesday and initiates a one time ATM transaction on Wednesday that would create an overdraft, you are not obligated to pay it.
Your argument to your processor is that the delay might cost you fees, not that it violates some regulation or regulatory intent.
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In this world you must be oh so smart or oh so pleasant. Well, for years I was smart. I recommend pleasant.